Publications

2024

S.J.D. Maessen, S. Lekanne Deprez, P. Vermeeren, B.W.L. van den Bersselaar, M. Lutz, J.P.A Heuts, C. Fonseca Guerra, A.R.A. Palmans: Structure-Property Relationships to Direct the Dynamic Properties of Acylsemicarbazide-Based Materials. Polym. Chem., Just accepted article (for Special issue: Fifteen years of Polymer Chemistry)

(DOI: 10.1039/D4PY01296H)

L. Rijns, H. Duijs, R. P. M. Lafleur, R. Cardinaels, A. R. A. Palmans, P. Y. W. Dankers, L. Su: Molecularly Engineered Supramolecular Thermoresponsive Hydrogels with Tunable Mechanical and Dynamic Properties. Biomacromolecules, 25, 4686–4696 (2024)

(DOI: 10.1021/acs.biomac.3c01357)

E. Archontakis, S. Dhiman, M. Zhang, M.E.J. Vleugels, E.W. Meijer, A.R.A. Palmans, P. Zijlstra, L. Albertazzi: Visualizing the Heterogeneity in Homogeneous Supramolecular Polymers. J. Am. Chem. Soc., 146, 19974–19985 (2024)

(DOI: 10.1021/jacs.4c03562)

A. Sathyan, E. Archontakis, A.J.H. Spiering, L. Albertazzi , A.R.A. Palmans: Effect of Particle Heterogeneity in Catalytic Copper-Containing Single-Chain Polymeric Nanoparticles Revealed by Single-Particle Kinetics. Molecules, 29, 1850 (2024)

(DOI:10.3390/molecules29081850)

L. Deng; A. R. Olea, A. Ortiz Perez, B. Sun, J. Wang, Silvia Pujals, A.R.A. Palmans, L. Albertazzi: Imaging diffusion and stability of single-chain polymeric nanoparticles in a multi-gel tumor-on-a-chip microfluidic device. Small Methods, 2301072 (2024)

(DOI:10.1002/smtd.202301072)

L. Deng, A. Sathyan, C. Adam, A. Unciti-Broceta, V. Sebastian, A. R. A. Palmans: Enhanced Efficiency of Pd(0)-Based Single Chain Polymeric Nanoparticles for in Vitro Prodrug Activation by Modulating the Polymers Microstructure. Nano Letters, 24, 2242–2249 (2024)

(DOI:10.1021/acs.nanolett.3c04466)

M. Vleugels, R. Bosman, P. da Camino, S. Wijker, B. Fehér, J. Spiering, L. Rijns, R. Bellan, P.Y.W. Dankers, A.R.A. Palmans: Bisurea-Based Supramolecular Polymers for Tunable Biomaterials” Chem. Eur. J., 30, e20230336 (2024)

(DOI: 10.1002/chem.202303361)

2023

A. Sathyan, T. Loman, L. Deng,  A.R.A. Palmans: Amphiphilic polymeric nanoparticles enable homogenous rhodium-catalysed NH insertion reactions in living cells. Nanoscale, 15, 12710-12717 (2023)

(DOI: 10.1039/D3NR02581K)

S. Wijker, A.R.A. Palmans: Protein-Inspired Control over Synthetic Polymer Folding for Structured Functional Nanoparticles in Water. ChemPlusChem, 88, e202300260ASAP (2023)

(DOI:10.1002/cplu.202300260)

S. Wijker, R. Monnink, L. Rijnders, L. Deng, A.R.A. Palmans: Simultaneously controlling conformational and operational stability of single-chain polymeric nanoparticles in complex media. Chem Commun., 59, 5407-5410 (2023).

(DOI: 10.1039/D3CC00763D)

R. Sarkar, S. Majumdar, S. Kuil, J. Mallens, J. J. B. van der Tol, R. P. Sijbesma, J. P. A. Heuts, A. R. A. Palmans: Dynamic covalent networks with tunable dynamicity by mixing acylsemicarbazides and thioacylsemicarbazides. J. Pol. Sci., 61, 1335 (2023)

(DOI: 10.1002/pol.20230068)

A. Sathyan. L. Deng. T. Loman, S. R. A. Palmans: Bio-orthogonal catalysis in complex media: Consequences of using polymeric scaffold materials on catalyst stability and activity. Catalysis Today, 418, 114116 (2023).

(DOI: 10.1016/j.cattod.2023.114116)

2022

E. Archontakis, L. Deng, P. Zijlstra, A. R. A. Palmans, L. Albertazzi: Spectrally PAINTing a Single Chain Polymeric Nanoparticle at Super-Resolution, J. Am. Chem. Soc., 144, 23698–23707 (2022)

(DOI: 10.1021/jacs.2c11940)

 A. Sathyan,   S. Croke,   A. Perez,   B. F M de Waal,   A. Unciti-Broceta,  A. R. A. Palmans: Developing Pd(II) based amphiphilic polymeric nanoparticles for pro-drug activation in complex media. Mol. Syst. Des. Eng., 7, 1736-1748 (2022)

(DOI: 10.1039/D2ME00173J)

J. J. B. van der Tol, G. Vantomme, A. R. A. Palmans, E. W. Meijer: Controlling the Processability and Stability of Supramolecular Polymers Using the Interplay of Intra- and Intermolecular Interactions. Macromolecules, 55, 6820–6829 (2022)

(DOI: 10.1021/acs.macromol.2c00976)

S. Wijker, L. Deng, F. Eisenreich, I. K. Voets, A. R. A. Palmans.  En Route to Stabilized Compact Conformations of Single-Chain Polymeric Nanoparticles in Complex Media. Macromolecules, 55, 6220–6230 (2022)

(DOI: 10.1021/acs.macromol.2c00930)

L. Su, J. Mosquera, M. F. J. Mabesoone, S. M. C. Schoenmakers, C. Muller, M. E. J. Vleugels, S. Dhiman, S. Wijker, A. R. A. Palmans, E. W. Meijer.  Dilution-induced gel-sol-gel-sol transitions by competitive supramolecular pathways in water. Science, 377, 213–218 (2022).

(DOI: 10.1126/science.abn3438)

F. Eisenreich, A. R. A. Palmans. Direct C-H trifluoromethylation of (hetero)arenes in water enabled by organic photoredox-active amphiphilic nanoparticles. Chem. Eur. J., 28, e202201322 (2022)

(DOI: 10.1002/chem.202201322)

S. M. C. Schoenmakers, A. J. H. Spiering, S. Herziger, C. Böttcher, R. Haag, A. R. A. Palmans, E. W. Meijer. Structure and Dynamics of Supramolecular Polymers: Wait and See. ACS MacroLett., 11, 711–715 (2022).

(DOI: 10.1021/acsmacrolett.2c00223)

M. L. Ślęczkowski, M. F. J. Mabesoone, M. D. Preuss, Y. Post, A. R. A. Palmans, E. W. Meijer. Helical bias in supramolecular polymers accounts for different stabilities of kinetically trapped states. J. Polym. Sci., 60, 1871-1877 (2022)

(DOI: 10.1002/pol.20220036)

L. Deng, L. Albertazzi, A.R.A. Palmans. Elucidating the Stability of Single Chain Polymeric Nanoparticles in Biological Media and Living Cells. Biomacromolecules, 23, 326–338 (2022).

(DOI:10.1021/acs.biomac.1c01291)

B. Lamers,   M. van Son,   F. V. de Graaf,   B. van den Bersselaar,   B. F. M. de Waal,   K. Komatsu,   H. Sato,   T. Aida,   J. A. Berrocal,   A. R. A. Palmans,   G. Vantomme,   S. C. J. Meskers,  E. W. Meijer. Tuning the donor-acceptor interactions in phase-segregated block molecules. Mater. Horiz., 9, 294-302 (2022)

(DOI:10.1039/D1MH01141C)

L.N.J. de Windt, Z. Fernández, M. Fernández-Míguez, F. Freire, A.R.A. Palmans. Elucidating the Supramolecular Copolymerization of N- and C-Centered Benzene-1,3,5-Tricarboxamides: The Role of Parallel and Antiparallel Packing of Amide Groups in the copolymer microstructure. Chem. Eur. J., 28, e202103691 (2022)

(DOI:10.1002/chem.202103691)   

2021

F. Eisenreich, A.R.A. Palmans in Supramolecular Catalysis: New Directions and Developments (Eds: P.W.N.M. van Leeuwen and M. Raynal). Chapter 33: Compartmentalized Polymers for Catalysis in Aqueous Media. (2021)

(DOI:10.1002/9783527832033.ch33)

M.E.J. Vleugels, S. Varela-Aramburu, B.F.M. de Waal, S.M.C. Schoenmakers, B. Maestro, A.R.A. Palmans, J.M. Sanz, E.W. Meijer. Choline-Functionalized Supramolecular Copolymers: Toward Antimicrobial Activity against Streptococcus pneumoniae. Biomacromolecules, 22, 5363–5373 (2021).

(DOI:10.1021/acs.biomac.1c01293

A. . Rösch, R. Reynaerts, B.A.G. Lamers, K.S. Mali, S. de Feyter, A.R.A. Palmans, E.W. Meijer. Double Lamellar Morphologies and Odd–Even Effects in Two- and Three-Dimensional N,N′-bis(n-alkyl)-naphthalenediimide Materials. Chem. Mater., 33, 8800–8811 (2021).

(DOI:10.1021/acs.chemmater.1c02898)

S. Varela-Aramburu, L. Su, J. Mosquera, G. Morgese, S. M. C. Schoenmakers, R. Cardinaels, A. R. A. Palmans, E. W. Meijer. Introducing Hyaluronic Acid into Supramolecular Polymers and Hydrogels. Biomacromolecules, 22, 4633–4641 (2021)

(DOI: 10.1021/acs.biomac.1c00927)

F. Eisenreich, T.H.R. Kuster, D. van Krimpen, A.R.A. Palmans. Photoredox-catalyzed Reduction of Halogenated Arenes in Water by Amphiphilic Polymeric Nanoparticles. Molecules, 26, 5882 (2021)

(DOI:10.3390/molecules26195882)

S.M.C. Schoenmakers, B.W.L. van den Bersselaar, S. Dhiman, L. Su, A.R.A. Palmans. Facilitating Functionalization of Benzene-1,3,5-Tricarboxamides by Switching Amide Connectivity. Org. Biomol. Chem., 19, 8281-8294 (2021)

(DOI:10.1039/D1OB01587G)

T. Iseki, M. F. J. Mabesoone, M. A. J. Koenis, B. A. G. Lamers, E. Weyandt, L. N. J. de Windt, W. J. Buma, A. R. A. Palmans,  E. W. Meijer. Temperature-dependent modulation by biaryl-based monomers of the chain length and morphology of biphenyl-based supramolecular polymers. Chem. Sci., 12, 13001-13012 (2021)

(DOI:10.1039/D1SC03974A )

A.T. Rösch, S.H.M. Söntjens, J. Robben, A.R.A. Palmans, T. Schnitzer. Rotational Isomerism of an Amide Substituted Squaraine Dye: A Combined Spectroscopic and Computational Study. J. Org. Chem., 86, 3100–13103 (2021)

(DOI:10.1021/acs.joc.1c00922)    

P. Chidchob, S.A.H. Jansen, S.C.J. Meskers, E. Weyandt, N.P. van Leest, B. de Bruin, A.R.A. Palmans, G. Vantomme, E.W. Meijer. Supramolecular Systems Containing B–N Frustrated Lewis Pairs of Tris(pentafluorophenyl)borane and Triphenylamine Derivatives. Organic Materials, 3, 174–183 (2021)

(DOI: 10.1055/s-0041-1727235)

B.A.G. Lamers, A. Herdlitschka, T. Schnitzer, M.F.J. Mabesoone, S.M.C. Schoenmakers, B.F.M. de Waal, A.R.A. Palmans, H. Wennemers, E.W. Meijer. Oligodimethylsiloxane-Oligoproline Block Co-Oligomers: the Interplay between Aggregation and Phase Segregation in Bulk and Solution. J. Am. Chem. Soc., 143, 4032–4042 (2021)

(DOI: 10.1021/jacs.1c01076)

X. Lou, S.M.C. Schoenmakers, J.L.J. van Dongen, M. Garcia-Iglesias, N.M. Casellas, M. Fernández-Castaño Romera, R.P. Sijbesma, E.W. Meijer, A.R.A. Palmans. Elucidating Dynamic Behaviour of Synthetic Supramolecular Polymers in Water by Hydrogen/Deuterium Exchange Mass Spectrometry. J. Polym. Sci., 59, 1151-1161 (2021)

(DOI: 10.1002/pol.20210011)

A. R. A. Palmans, E. W. Meijer, S. E. Denmark. Stereochemical Language in Supramolecular Polymer Chemistry: How We Can Do Better. J. Pol. Sci., 59, 1171-1174 (2021)

(DOI: 10.1002/pol.20200814)

Y. Abdouni, G.M. ter Huurne, G. Yilmaz, A. Monaco, C. Redondo-Gómez, E. W Meijer, A. R. A. Palmans, C. Remzi Becer. Self-Assembled Multi and Single Chain Glyconanoparticles and Their Lectin Recognition. Biomacromolecules, 22, 661–670 (2021)

(DOI: 10.1021/acs.biomac.0c01486)

C. Kulkarni, R.H.N. Curvers, G. Vantomme, D.J. Broer, A.R.A. Palmans, S.C.J. Meskers, and E.W. Meijer. Consequences of Chirality in Directing the Pathway of Cholesteric Helix Inversion of π‐Conjugated Polymers by Light. Adv. Mater., 33, 2005720 (2021)

(DOI: 10.1002/adma.202005720)

M. L. Ślęczkowski, M. F. J. Mabesoone, P. Ślęczkowski, A. R. A. Palmans and E. W. Meijer: Competition between chiral solvents and chiral monomers in the helical bias of supramolecular polymers. Nature Chem., 13, 200–207 (2021)

(DOI: 10.1038/s41557-020-00583-0)

2020

M.F.J. Mabesoone, A.R.A. Palmans ARA, E.W. Meijer: Solute–Solvent Interactions in Modern Physical Organic Chemistry: Supramolecular Polymers as a Muse. J. Am. Chem. Soc., 142, 47, 19781–19798 (2020)

(DOI: 10.1021/jacs.0c09293)

B.A.G. Lamers, J.J.B. van der Tol, K.M. Vonk, B.F.M. de Waal, A.R.A. Palmans, E.W. Meijer, and G. Vantomme. Consequences of Molecular Architecture on the Supramolecular Assembly of Discrete Block Co-oligomers. Macromolecules,  53, 10289–10298 (2020).

(DOI: 10.1021/acs.macromol.0c02237)

N.J.van Zee, M.F.J. Mabesoone, B. Adelizzi, A.R.A. Palmans, E.W. Meijer: Biasing the Screw-Sense of Supramolecular Coassemblies Featuring Multiple Helical States. J. Am. Chem. Soc., 142, 20191–20200 (2020).

(DOI: 10.1021/jacs.0c10456)

R.P.M. Lafleur, S. Herziger, S.M.C. Schoenmakers, A.D.A. Keizer, J. Jahzerah, B.N.S. Thota, L. Su, P.H.H. Bomans, N.A.J.M. Sommerdijk, A.R.A. Palmans, R. Haag, H. Friedrich, Christoph Böttcher, and E. W. Meijer. Supramolecular Double Helices from Small C3-Symmetrical Molecules Aggregated in Water. J. Am. Chem. Soc., 142, 17644–17652 (2020).

(DOI: 10.1021/jacs.0c08179)

M.L. Ślęczkowski, I. Segers, Y. Liu, A.R.A. Palmans: Sequence-defined l-glutamamide oligomers with pendant supramolecular motifs via iterative synthesis and orthogonal post-functionalization. Polym. Chem., 11, 7393-7401 (2020).

(DOI: 10.1039/D0PY01157F)

M.E.J. Vleugel, M.E. de Zwart, J.R. Magana, B.A.G. Lamers, I.K Voets, E.W. Meijer, K. Petkau-Milroy, A.R.A. Palmans: Effect of crystallinity and dispersity on the self-assembly behavior of block co-oligomers in water. Polym. Chem., 11, 7170-7177 (2020).

(DOI: 10.1039/D0PY01161D)

S. Varela-Aramburu, G. Morgese, L. Su, S.M.C. Schoenmakers, M. Perrone, L. Leanza, C. Perego, G.M. Pavan, A.R.A. Palmans, and E. W. Meijer. Exploring the Potential of Benzene-1,3,5-tricarboxamide Supramolecular Polymers as Biomaterials. Biomacromolecules, 21, 4105–4115 (2020).

(DOI: 10.1021/acs.biomac.0c00904)

B. Adelizzi, P. Chidchob, N. Tanaka, B.A.G. Lamers, S.C.J. Meskers, S. Ogi, A.R.A. Palmans, S. Yamaguchi, and E.W. Meijer. Long-Lived Charge-Transfer State from B-N Frustrated Lewis Pairs Enchained in Supramolecular Copolymers. J. Am. Chem. Soc., 142, 16681–16689 (2020).

(DOI: 10.1021/jacs.0c06921)

G. Morgese, B.F.M. de Waal, S. Varela‐Aramburu, A.R.A. Palmans, L. Albertazzi, E.W. Meijer. Anchoring Supramolecular Polymers to Human Red Blood Cells by Combining Dynamic Covalent and Non‐Covalent Chemistries. Angew. Chem. Int. Ed., 59, 17229–17233 (2020).

(DOI: 10.1002/ange.202006381)

A.T. Rösch, Q. Zhu, J. Robben, F. Tassinari, S.C.J. Meskers, R. Naaman, A.R.A. Palmans, and E.W. Meijer. Helicity control in the aggregation of achiral squaraine dyes in solution and thin films. Chem. Eur. J., 27, 298 –306 (2021).

(DOI: 10.1002/chem.202002695)

M.F.J. Mabesoone, G.M. ter Huurne, A.R.A. Palmans, and E.W. Meijer. How Water in Aliphatic Solvents Directs the Interference of Chemical Reactivity in a Supramolecular System. J. Am. Chem. Soc., 142, ‏ 1240–12408 (2020).

(DOI: 10.1021/jacs.0c04962)

C. Mertens, M. Soete, M.L. Ślęczkowski, A.R.A. Palmans, E.W. Meijer, N. Badi, and F. Du Prez. Stereocontrolled, multi-functional sequence-defined oligomers through automated synthesis. Polym. Chem., 11, 4271–4280 (2020).

(DOI: 10.1039/D0PY00645A)

F. Eisenreich, E.W. Meijer, and A.R.A. Palmans. Amphiphilic Polymeric Nanoparticles for Photoredox Catalysis in Water. Chem. Eur. J., 26, 10355–10361 (2020).

(DOI: 10.1002/chem.202001767)

G. M. ter Huurne, P. Chidchob, A. Long, A. Martinez , A.R.A. Palmans, and G. Vantomme. Controlling the Length of Cooperative Supramolecular Polymers with Chain Cappers. Chem. Eur. J., 26, 9964–9970 (2020).

(DOI:10.1002/chem.202001293)

M.F.J. Mabesoone, S. Kardas, H. Soria-Carrera, J. Barberá, J.M. de la Fuente, A.R.A. Palmans, M. Fossépré, M. Surin, and R. Martín-Rapún. Competitive hydrogen bonding in supramolecular polymerizations of tribenzylbenzene-1,3,5-tricarboxamides. Mol. Syst. Des. Eng., 5, 820–828 (2020).

(DOI: 10.1039/d0me00030b)

E. Weyandt, M.F.J. Mabesoone, L.N.J. de Windt, E. W. Meijer, A.R. A. Palmans, and G. Vantomme. How to Determine the Role of an Additive on the Length of Supramolecular Polymers. Organic Materials, 2, 129–142 (2020).

 (DOI: 10.1055/s-0040-1708813)

B.A.G. Lamers, M.L. Ślęczkowski, F. Wouters, T. Engels, E. W. Meijer, and A. Palmans. Tuning polymer properties of non-covalent crosslinked PDMS by varying supramolecular interaction strength. Polym. Chem., 11, 2847–2854 (2020).

(DOI: 10.1039/D0PY00139B)

E. Weyandt, G.M. ter Huurne, G. Vantomme, A.J. Markvoort, A.R.A. Palmans, and E.W. Meijer. Photo-dynamic control of the chain length in supramolecular polymers; switching an intercalator into a chain-capper. J. Am. Chem. Soc., 142, 13, 6295–6303 (2020).

(DOI: 10.1021/jacs.0c00858)

E. Weyandt and A.R.A. Palmans. Better Together: Enhanced Phosphorescence and Coassembly of Pt-Pd Complexes, Chem, 6, 808–831 (2020)

(DOI: 10.1016/j.chempr.2020.03.001).

2019

K. Petkau-Milroy, A. Ianiro, M.M.L. Ahn, J.R. Magana, M.E.J. Vleugels, B.A.G. Lamers, R. Tuinier, I.K. Voets, A.R.A. Palmans, E.W. Meijer. Architecture-Dependent Interplay between Self-Assembly and Crystallization in Discrete Block Co-Oligomers. ACS MacroLett., 9, 38–42 (2019).

(DOI: 10.1021/acsmacrolett.9b00814)

H.M.M. ten Eikelder, B. Adelizzi,A.R.A. Palmans, A.J. Markvoort: Equilibrium Model for Supramolecular Copolymerizations. J. Phys. Chem. B, 123, 6627–6642 (2019).

(DOI: 10.1021/acs.jpcb.9b04373)

J.A. Berrocal, M.F.J. Mabesoone, M. Garcia Iglesias, A. Huizinga, E.W. Meijer, and A.R.A. Palmans. Selenoamides modulate dipole–dipoleinteractions in hydrogen bonded supramolecularpolymers of 1,3,5-substituted benzenes. Chem. Commun., 55, 14906–14909 (2019).

(DOI: 10.1039/c9cc08423a)

G. Vantomme, G.M. ter Huurne, C. Kulkarni, H.M.M. ten Eikelder, A.J. Markvoort, A.R.A. Palmans, and E. W. Meijer. Tuning the Length of Cooperative Supramolecular Polymers under Thermodynamic Control. J. Am. Chem. Soc., 141, 18278–18285 (2019).

(DOI: 10.1021/jacs.9b09443)

L.N.J. de Windt, C. Kulkarni, H.M.M. ten Eikelder, A.J. Markvoort, E.W. Meijer, and A.R.A. Palmans. Detailed Approach to Investigate Thermodynamically Controlled Supramolecular Copolymerizations. Macromolecules, 52, 19, 7430-7438 (2019).

(DOI: 10.1021/acs.macromol.9b01502).

B.A.G. Lamers, R. Graf, B.F.M. de Waal, G. Vantomme, A.R.A. Palmans, and E.W. Meijer. Polymorphism in the Assembly of Phase-Segregated Block Molecules: Pathway Control to 1D and 2D Nanostructures. J. Am. Chem. Soc., 141, 15456–15463 (2019).

(DOI: 10.1021/jacs.9b08733)

C. Kulkarni, M.H.C. van Son, D. Di Nuzzo, S.C.J. Meskers, A.R.A. Palmans, and E.W. Meijer. Molecular Design Principles for Achieving Strong Chiroptical Properties of Fluorene Copolymers in Thin-Films. Chem. Mater., 31, 6633-6641 (2019).

(DOI: 10.1021/acs.chemmater.9b00601)

B. Adelizzi, A.T. Rösch, D.J. van Rijen, R.S. Martire, S. Esiner, M. Lutz, A.R.A. Palmans, and E.W. Meijer. Chiral Aggregates of Triphenylamine‐Based Dyes for Depleting the Production of Hydrogen Peroxide in the Photochemical Water‐Splitting Process. Helv. Chim. Acta, 102, e19000 (2019).

(DOI: 10.1002/hlca.201900065).

G.M. ter Huurne, A.R.A. Palmans, and E.W. Meijer. Supramolecular Single-Chain Polymeric Nanoparticles. CCS Chem., 1, 64 (2019).

(DOI: 10.31635/ccschem.019.20180036).

R.P.M. Lafleur, S.M.C. Schoenmakers, P. Madhikar, D. Bochicchio, B. Baumeier, A.R.A. Palmans, G.M. Pavan, and E. W. Meijer. Insights into the Kinetics of Supramolecular Comonomer Incorporation in Water. Macromolecules, 52, 3049–3055 (2019).

(DOI: 10.1021/acs.macromol.9b00300)

C. Kulkarni, J.A. Berrocal, M. Lutz, A.R.A. Palmans, and E.W. Meijer. Directing the Solid-State Organization of Racemates via Structural Mutation and Solution-State Assembly Processes. J. Am. Chem. Soc., 141, 6302–6309 (2019).

(DOI: 10.1021/jacs.9b00452)

B. Adelizzi, N. Van Zee, L. de Windt, A.R.A. Palmans, and E.W. Meijer. The future of supramolecular copolymers unveiled by reflecting on covalent copolymerization. J. Am. Chem. Soc., 141, 6110–6121 (2019).

(DOI: 10.1021/jacs.9b01089)

B.A.G. Lamers, B. van Genabeek, J. Hennissen, B.F.M. de Waal, A.R.A. Palmans , and E.W. Meijer. Stereocomplexes of Discrete, Isotactic Lactic Acid Oligomers Conjugated with Oligodimethylsiloxanes. Macromolecules, 52, 1200-1209 (2019).

(DOI: 10.1021/acs.macromol.8b02529).

G.M. ter Huurne, G. Vantomme, B.W.L. van den Bersselaar, B.N.S. Thota, I.K. Voets, A.R.A. Palmans, E.W. Meijer. The effect of dendritic pendants on the folding of amphiphilic copolymers via supramolecular interactions. J. Polym. Sci. A Polym. Chem., 57, 411-421 (2019).

(DOI: 10.1002/pola.29223)

2018

G.M. ter Huurne, I.K. Voets, A.R.A. Palmans and E.W. Meijer. Effect of Intra- versus Intermolecular Cross-Linking on the Supramolecular Folding of a Polymer Chain. Macromolecules, 51, 8853–8861 (2018).

(DOI: 10.1021/acs.macromol.8b01623)

N.M. Matsumoto, R.P.M. Lafleur, X. Lou, K.-C. Shih, S.P.W. Wijnands, C. Guibert, J.W.A.M. van Rosendaal, I.K. Voets, A.R.A. Palmans, Y. Lin, and E.W. Meijer. Polymorphism in Benzene-1,3,5-tricarboxamide Supramolecular Assemblies in Water: A Subtle Trade-off between Structure and Dynamics. J. Am. Chem. Soc., 140, 13308–13316 (2018).

(DOI: 10.1021/jacs.8b07697)

S.M.C. Schoenmakers, C.M.A. Leenders, R.P.M. Lafleur, X. Lou, E.W. Meijer, G.M. Pavan and A.R.A. Palmans. Impact of the water-compatible periphery on the dynamic and structural properties of benzene-1,3,5-tricarboxamide based amphiphiles. Chem. Commun., 54, 11128–11131 (2018).

(DOI: 10.1039/C8CC04818E).

C. Kulkarni, S.C.J. Meskers, A.R.A. Palmans, and E.W. Meijer. Amplifying Chiroptical Properties of Conjugated Polymer Thin-Film Using an Achiral Additive. Macromolecules, 51, 5883–5890 (2018).

(DOI: 10.1021/acs.macromol.8b0107)

Y. Liu, P. Turunen, B.F.M. de Waal, K.G. Blank, A.E. Rowan, A.R.A. Palmans and E.W. Meijer. Catalytic single-chain polymeric nanoparticles at work: from ensemble towards single-particle kinetics. Mol. Syst. Des. Eng., 3, 609-618 (2018).

(DOI: 10.1039/c8me00017d)

R.P.M. Lafleur, X. Lou, G.M. Pavan, A.R.A. Palmans and E.W. Meijer, Consequences of a cosolvent on the structure and molecular dynamics of supramolecular polymers in water. Chem. Sci., 9, 6199-6209 (2018).

(DOI: 10.1039/c8sc02257g)

M.F.J. Mabesoone, A.J. Markvoort, M. Banno, T. Yamaguchi, F. Helmich, Y. Naito, E. Yashima, A.R.A. Palmans, and E.W. Meijer. Competing Interactions in Hierarchical Porphyrin Self-Assembly Introduce Robustness in Pathway Complexity. J. Am. Chem. Soc., 140, 7810–7819 (2018).

(DOI: 10.1021/jacs.8b02388).

N.J. Van Zee, B. Adelizzi, M.F.J. Mabesoone, X. Meng, A. Aloi, R.H. Zha, M. Lutz, I.A.W. Filot, A.R.A. Palmans & E.W. Meijer. Potential enthalpic energy of water in oils exploited to control supramolecular structure. Nature, 558, 100–103 (2018).

(DOI: 10.1038/s41586-018-0169-0)

B. Adelizzi, A. Aloi, A.J. Markvoort, H.M.M. ten Eikelder, I.K. Voets, A.R.A. Palmans, and E.W. Meijer. Supramolecular block copolymers under thermodynamic control. J. Am. Chem. Soc., 140, 7168–7175 (2018).

(DOI: 10.1021/jacs.8b02706)

B.N.S. Thota, X. Lou, D, Bochicchio, T.F.E. Paffen, R.P.M. Lafleur, J.L.J. van Dongen, S. Ehrmann, R. Haag, G.M. Pavan, A.R.A. Palmans, E.W. Meijer. Supramolecular Copolymerization as a Strategy to Control the Stability of Self‐Assembled Nanofibers. Angew. Chem. Int. Ed., 57, 6843 –6847 (2018).

(DOI: 10.1002/anie.201802238)

B. Adelizzi,* A. Aloi,* N.J. Van Zee, A.R.A. Palmans, E.W. Meijer, and I.K. Voets. Painting Supramolecular Polymers in Organic Solvents by Super-Resolution Microscopy. ACS Nano, 12, 4431–4439 (2018).

(DOI: 10.1021/acsnano.8b00396)

B. van Genabeek, B.F.M de Waal, A. Palmans and E.W. Meijer. Discrete oligodimethylsiloxane–oligomethylene di- and triblock co-oligomers: synthesis, self-assembly and molecular organisation. Polym. Chem., 9, 2746–2758 (2018).

(DOI: 10.1039/c8py00355f)

A. Das, K. Petkau-Milroy, G. Klerks, B. van Genabeek, R.P.M. Lafleur, A.R.A. Palmans, and E.W. Meijer. Consequences of Dispersity on the Self-Assembly of ABA-Type Amphiphilic Block Co-Oligomers. ACS MacroLett., 7, 546–550 (2018).

(DOI: 10.1021/acsmacrolett.8b00168)

Y. Liu, S. Pujals, P.J.M. Stals, T. Paulöhrl, S.I. Presolski, E.W. Meijer, L. Albertazzi, and A.R.A. Palmans. Catalytically Active Single-Chain Polymeric Nanoparticles: Exploring Their Functions in Complex Biological Media. J. Am. Chem. Soc., 140, 3423–3433 (2018).

(DOI: 10.1021/jacs.8b00122).

2017

M.L. Ślęczkowski, E.W. Meijer, A.R.A. Palmans. Cooperative Folding of Linear Poly(dimethyl siloxane)s via Supramolecular Interactions. Macromol. Rapid Commun., 1700566 (2017).

(DOI: 10.1002/marc.201700566)

G.M. ter Huurne, L.N.J. de Windt, Y. Liu, E.W. Meijer, I.K. Voets, and A.R.A. Palmans. Improving the Folding of Supramolecular Copolymers by Controlling the Assembly Pathway Complexity. Macromolecules, 50, 8562–8569 (2017).

(DOI: 10.1021/acs.macromol.7b01769)

B. Van Genabeek, B. Lamers, B.F.M. de Waal, M. Van Son, A.R.A. Palmans, and E.W. Meijer. Amplifying (im)perfection: The Impact of Crystallinity in Discrete and Disperse Block Co-oligomers. J. Am. Chem. Soc., 139, 14869–14872 (2017).

(DOI: 10.1021/jacs.7b08627)

C. Kulkarni, P.A. Korevaar, K.K. Bejagam, A.R.A. Palmans, E.W. Meijer, and S.J. George, Solvent Clathrate Driven Dynamic Stereomutation of a Supramolecular Polymer with Molecular Pockets. J. Am. Chem. Soc., 139, 13867–13875 (2017).

(DOI: 10.1021/jacs.7b07639)

C. Kulkarni, E. W. Meijer, and A.R.A. Palmans, Cooperativity Scale: A Structure–Mechanism Correlation in the Self-Assembly of Benzene-1,3,5-tricarboxamides. Acc. Chem. Res., 50, 1928–1936 (2017).

(DOI: 10.1021/acs.accounts.7b00176)

B. van Genabeek, B.F.M. de Waal, B. (DOI: 10.1021/acsmacrolett.7b00266), A.R.A. Palmans, and E.W. Meijer, Dispersity under Scrutiny: Phase Behavior Differences between Disperse and Discrete Low Molecular Weight Block Co-Oligomers, ACS MacroLett., 6, 674–678 (2017).

A. Das, G. Vantomme, A.J. Markvoort, H.M.M. ten Eikelder, M. Garcia-Iglesias, A.R.A. Palmans, and E.W. Meijer, Supramolecular Copolymers: Structure and Composition Revealed by Theoretical Modeling, J. Am. Chem. Soc., 139, 7036–7044 (2017).

(DOI: 10.1021/jacs.7b02835)

X. Lou*, R.P.M. Lafleur*, C.M.A. Leenders, S.M.C. Schoenmakers, N.M. Matsumoto, M.B. Baker, J.L.J. van Dongen, A.R.A. Palmans and E.W. Meijer, Dynamic diversity of synthetic supramolecular polymers in water as revealed by hydrogen/deuterium exchange, Nature Communications, 8, 15420 (2017).

(DOI: 10.1038/ncomms15420).

Y. Ogura, M. Artar, A.R.A. Palmans, M. Sawamoto, E.W. Meijer and T. Terashima, Self-Assembly of Hydrogen-Bonding Gradient Copolymers: Sequence Control via Tandem Living Radical Polymerization with Transesterification, Macromolecules, 50, 3215–3223 (2017).

(DOI: 10.1021/acs.macromol.7b00070)

W. Mtangi, F. Tassinari, K. Vankayala, A. Vargas Jentzsch, B. Adelizzi, A.R.A. Palmans, C. Fontanesi, E.W. Meijer, R. Naaman, Control of Electrons’ Spin Eliminates Hydrogen Peroxide Formation During Water Splitting, J. Am. Chem. Soc., 139, 7, 2794–2798 (2017).

(DOI: 10.1021/jacs.6b12971)

A.R.A. Palmans, Deracemisations under kinetic and thermodynamic control, Mol. Syst. Des. Eng., 2, 34-46 (2017).

(DOI: 10.1039/C6ME00088F)

B. Adelizzi, I.A.W. Filot, A.R.A. Palmans, E.W. Meijer, Unravelling the Pathway Complexity in Conformationally Flexible N-Centered Triarylamine Trisamides, Chem. Eur. J. 23, 6103 (2017).

2016

M. Garzoni, M.B. Baker, C.M.A. Leenders, I.K. Voets, L. Albertazzi, A.R.A. Palmans, E.W. Meijer, G.M. Pavan, Effect of H-bonding on order amplification in the growth of a supramolecular polymer in water, J. Am. Chem. Soc., 138, 13985-13995 (2016).

(DOI: 10.1021/jacs.6b07530)

J.A. Berrocal, F. Di Meo, M. Garcia-Iglesias, R.P.J. Gosens, E.W. Meijer, M. Linares, A.R.A. Palmans, Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes, Chem. Commun. 52, 10870-10873 (2016).

(DOI: 10.1039/C6CC05593A)

M. García-Iglesias, B.F.M. de Waal, A.V. Gorbunov, A.R.A. Palmans, M. Kemerink, E.W. Meijer, A Versatile Method for the Preparation of Ferroelectric Supramolecular Materials via Radical End-Functionalization of Vinylidene Fluoride Oligomers. J. Am. Chem. Soc., 138, 6217–6223 (2016).

(DOI: 10.1021/jacs.6b01908)

A.J.P. Teunissen, R.J.C. van der Haas, J.A.J.M. Vekemans, A.R.A. Palmans, E.W. Meijer, Scope and Limitations of Supramolecular Autoregulation. Bull. Chem. Soc. Jpn., 89, 308-314 (2016).

(DOI: 10.1246/bcsj.20150407)

B. van Genabeek, B.F.M. de Waal, M.M.J. Gosens, L.M. Pitet, A.R.A. Palmans, E.W. Meijer, Synthesis and Self-assembly of Discrete Dimethylsiloxane-Lactic Acid Diblock Co-oligomers; the Dononacontamer and its Shorter Homologues. J. Am. Chem. Soc., 138, 4210–4218 (2016).

(DOI: 10.102/jacs.6b00629)

C.M.A. Leenders, G. Jansen, M.M.M. Frissen, R.P.M. Lafleur, I.K. Voets, A.R.A. Palmans, E.W. Meijer, Monosaccharides as Versatile Units for Water-Soluble Supramolecular Polymers. Chem. Eur. J., 22, 4608–4615 (2016).

(DOI: 10.1002/chem.201504762)

C.M.A. Leenders, M.B. Baker, I.A.B. Pijpers, R.P.M. Lafleur, L. Albertazzi, A.R.A. Palmans, E.W. Meijer, Supramolecular polymerisation in water; elucidating the role of hydrophobic and hydrogen-bond interactions. Soft Matter, 12, 2887-2893 (2016).

(DOI: 10.1039/C5SM02843D)

P.J.M. Stals, C-Y Cheng, L. van Beek, A.C. Wauters, A.R.A. Palmans, S. Han, E.W. Meijer, Surface Water Retardation around Single-Chain Polymeric Nanoparticles: Critical for Catalytic Function? Chem. Sci., 7, 2011-2015 (2016).

(DOI: 10.1039/C5SC02319J).


 M.B. Baker, R.P.J. Gosens, L. Albertazzi, N.M. Matsumoto, A.R.A. Palmans, E.W. Meijer, Exposing differences in monomer exchange rates of multicomponent supramolecular polymers in water, ChemBioChem., 17, 207-2013 (2016).

(DOI: 10.1002/cbic.201500606)

2015

O. Altintas, M. Artar, G. ter Huurne, I.K. Voets, A.R.A. Palmans, C. Barner-Kowollik, E.W. Meijer, Design and Synthesis of Triblock Copolymers for Creating Complex Secondary Structures by Orthogonal Self-Assembly. Macromolecules, 48, 8921–8932 (2015).

(DOI: 10.1021/acs.macromol.5b01990)

L. Albertazzi, N. van der Veeken, M.B. Baker, A.R.A. Palmans, E.W. Meijer, Supramolecular copolymers with stimuli-responsive sequence control. Chem Commun., 51, 16166–16168 (2015).

(DOI: 10.1039/C5CC06951C)

Y. Liu, T. Pauloehrl, S.I. Presolski, L. Albertazzi, A.R. A. Palmans, E.W. Meijer, Modular Synthetic Platform for the Construction of Functional Single-Chain Polymeric Nanoparticles: From Aqueous Catalysis to Photosensitization, J. Am. Chem. Soc., 137, 13096-13105 (2015).

(DOI: 10.1021/jacs.5b08299)

M. Artar, E.R.J Souren, T. Terashima, E.W. Meijer, A.R.A. Palmans, Single Chain Polymeric Nanoparticles as Selective Hydrophobic Reaction Spaces in Water. ACS MacroLett., 4, 1099–1103 (2015).

(DOI: acsmacrolett.5b00652)

L.N. Neumann, M.B. Baker, C.M.A. Leenders, I.K. Voets, R.P.M. Lafleur, A.R.A. Palmans, E.W. Meijer, Supramolecular polymers for organocatalysis in water, Org. Biomol. Chem., 13, 7711-7719 (2015).

(DOI: 10.1039/c5ob00937e)

G.M. ter Huurne, M.A.J. Gilissen, A.R.A. Palmans, I.K. Voets, E.W. Meijer, The coil-to-globule transition of single-chain polymeric nanoparticles with a chiral internal secondary structure, Macromolecules, 48, 3949-3956 (2015).

(DOI: 10.1021/acs.macromol.5b00604)

 N. Hosono, A.M. Kushner, J. Chung, A.R.A. Palmans, Z.B. Guan, E.W. Meijer, Forced unfolding of single-chaing polymeric nanoparticles, J. Am. Chem. Soc., 137, 6880-6888 (2015).

(DOI: 10.1021/jacs.5b02967)

M.B. Baker, L. Albertazzi, I.K. Voets, C.M.A. Leenders, A.R.A. Palmans, G.M. Pavan, E.W. Meijer, Consequences of chirality on the dynamics of a water-soluble supramolecular polymer, Nature Communications, 6, 6234 (2015).

(DOI: 10.1038/ncomms7234) 

E. Huerta, B. van Genabeek, B.A.G. Lamers, M.M.E. Koenigs, E.W. Meijer, A.R.A. Palmans, Triggering activity of catalytic rod-like supramolecular polymers, Chem. Eur. J., 21, 3682-3690 (2015).

(DOI: 10.1002/chem.201405410)

P.J.M. Stals, M. Artar, P. Vendrig, A.R.A. Palmans, E.W. Meijer, Consequences of subtle chiral effects: from “majority-rules” to “minority-rules”, Aust. J. Chem., 68, 622-626 (2015).

(DOI: 10.1071/CH14596).

M. Garcia-Iglesias, B.F.M. de Waal, I. de Feijter, A.R.A. Palmans, E.W. Meijer, Nanopatterned superlattices in self-assembled C-2-symmetric oligodimethylsiloxane-based benzene-1,2,3-tricarboxamides, Chem. Eur. J., 21, 377-385 (2015).

(DOI: 10.1002/chem.201404375)

de Feijter I, Albertazzi LA, Palmans ARA, Voets IK: Stimuli-Responsive Colloidal Assembly Driven by Surface-Grafted Supramolecular Moieties. Langmuir, 2015, 31, 57–64.

(DOI: 10.1021/la5031872)

1995-2014

  1. Palmans ARA, Vekemans JAJM, Meijer, E. W. Intramolecular H-bonding in acylated 2,2′-bipyridine-3,3′-diamines. Recl. Trav. Chim. Pays-Bas 1995, 114, 277–284.
  2. Vekemans JAJM, Groenendaal L, Palmans ARA, Delnoye DAP, Van Mullekom HAM, Meijer EW: Coplanarity by H-bonding in well-defined oligoheterocycles. Bull. Soc. Chim. Belges1996, 105, 659–674.
  3. Palmans ARA, Vekemans JAJM, Havinga EE, Meijer EW: Sergeants-and-soldiers principle in chiral columnar stacks of disc-shaped molecules with C3-symmetry. Angew. Chem. Int. Ed. Eng.1997, 36, 2648–2651. (DOI: 10.1002/anie.199726481)
  4. Palmans ARA, Vekemans JAJM, Meijer EW, Kooijman H, Spek AL: Hydrogen-bonded porous solid derived from trimesic amide. Chem. Commun.1997, 2247–2248. (DOI: 10.1039/a705339h)
  5. Palmans ARA, Vekemans JAJM, Fischer H, Hikmet RA, Meijer EW: Extended-core discotic liquid crystals based on the intramolecular H-bonding in N-acylated 2,2′-bipyridine-3,3′-diamine moieties. Chem. Eur. J.1997, 3, 300–307. (DOI: 10.1002/chem.19970030220)
  6. Palmans ARA, Vekemans JAJM, Hikmet RA, Fischer H, Meijer EW: Lyotropic liquid-crystalline behavior in disk-shaped compounds incorporating the 3,3′-di(acylamino)-2,2′-bipyridine unit. Adv. Mater. 1998, 10, 873–875.
  7. Palmans ARA, Smith P, Weder C: Polarizing Energy Transfer in Photoluminescent Conjugated Polymers with Covalently Attached Sensitizers. Macromolecules1999, 32, 4677–4685. (DOI:10.1021/ma990183d)
  8. Eglin M, Montali A, Palmans ARA, Tervoort T, Smith P, Weder C: Ultra-high performance photoluminescent polarizers based on melt-processed polymer blends. J. Mater. Chem.1999, 9, 2221–2226. (DOI:10.1039/a902864a)
  9. Palmans ARA, Eglin M, Montali A, Weder C, Smith P: Tensile orientation behavior of alkoxy-substituted bis(phenylethynyl)benzene derivatives in polyolefin blend films. Chem. Mater. 2000, 12, 472–480. (DOI:10.1021/cm990558)
  10. Montali A, Palmans ARA, Eglin M, Weder C, Smith P, Trabesinger W, Renn A, Hecht B, Wild UP: Phase behavior and anisotropic optical properties of photoluminescent polarizers. Macromol. Symp. 2000, 154, 105–116. (DOI: 10.1002/1521-3900(200004)154)
  11. Montali A, Palmans ARA, Bras J, Pepin-Donat B, Guillerez S, Smith P, Weder C: Depolarizing energy transfer in photoluminescent polymer blends. Synth. Met.2000, 115, 41–45. (DOI: 10.1016/S0379-6779(00)00298-8)
  12. Meyer U, Palmans ARA, Loontjens T, Heise A: Enzymatic ring-opening polymerization and atom transfer radical polymerization from a bifunctional initiator. Macromolecules2002, 35, 2873-2875. (DOI:10.1021/ma011929m)
  13. Ojelund K, Loontjens T, Steeman P, Palmans A, Maurer F: Synthesis, structure and properties of melamine-based pTHF-urethane supramolecular compounds. Macromol. Chem. Phys. 2003, 204, 52-60. (DOI:10.1002/macp.200290055)
  14. Peeters JW, Palmans ARA, Veld M, Scheijen F, Heise A, Meijer EW: Cascade synthesis of chiral block copolymers combining lipase catalysed ring opening polymerisation and atom transfer radical polymerization. Biomacromolecules 2004, 5, 1862–1868. (DOI: 10.1021/bm049794q1862)
  15. van As BAC, Thomassen P, Palmans ARA, Kalra B, Gross RA, Heise A: One-pot chemoenzymatic cascade polymerization under kinetic resolution conditions. Macromolecules 2004, 37, 8973–8977. (DOI:10.1021/ma048827r)
  16. Peeters JW, van Leeuwen O, Palmans ARA, Meijer EW: Lipase-Catalyzed Ring-Opening Polymerizations of 4-Substituted e-Caprolactones: Mechanistic Considerations. Macromolecules 2005, 38, 5587–5592. (DOI:10.1021/ma050510j)
  17. van As BAC, van Buijtenen J, Heise A, Broxterman QB, Verzijl GKM, Palmans ARA, Meijer EW: Chiral oligomers by iterative tandem catalysis. J. Am. Chem. Soc. 2005, 127, 9964-9965. (DOI:10.1021/ja052347d)
  18. van Gestel J, Palmans ARA, Titulaer B, Vekemans JAJM, Meijer EW: “Majority-Rules” operative in chiral columnar stacks of C3-symmetrical molecules. J. Am. Chem. Soc. 2005, 127, 5490–5494. (DOI:10.1021/ja0501666)
  19. Peeters JW, Palmans ARA, Meijer EW, Koning CE, Heise A: Chemoenzymatic synthesis of branched polymers. Macromol. Rapid Commun. 2005, 26, 684-689. (DOI: 10.1002/marc.200500011)
  20. de Geus M, Peeters J, Wolffs M, Hermans T, Palmans ARA, Koning CE, Heise A: Investigation of factors influencing the chemo-enzymatic synthesis of block copolymers. Macromolecules 2005, 38, 4220–4225. (DOI:10.1021/ma0473871)
  21. Magusin PCMM, Mezari B, Van der Mee L, Palmans ARA, Meijer EW: Novel biodegradable poly(pentadecalactone-co-oxocrown ether) studied with solid state NMR. Macromol. Symp. 2005, 230, 126-132. (DOI:10.1002/masy.200551151)
  22. van der Mee L, Antens J, van de Kruijs B, Palmans ARA, Meijer EW: Oxo-crown-ethers as co-monomers for tuning polyester properties. J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 2166-2176. (DOI:10.1002/pola.2132)
  23. van Buijtenen J, van As BAC, Meuldijk J, Palmans ARA, Vekemans JAJM, Hulshof LA, Meijer EW: Chiral polymers by iterative tandem catalysis. Chem. Commun. 2006, 3169-3171. (DOI:10.1039/b606241e)
  24. De Geus M, Schormans L, Palmans ARA, Koning CE, Heise A: Block copolymers by chemoenzymatic cascade polymerization: a comparison of consecutive and simultaneous reactions. J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 4290-4297. (DOI: 10.1002/pola.21528)
  25. Van der Mee L, Helmich F, De Bruijn R, Vekemans JAJM, Palmans ARA, Meijer EW: Investigation of lipase-catalyzed ring-opening polymerizations of lactones with various ring sizes: kinetic evaluation. Macromolecules 2006, 39, 5021–5027. (DOI: 10.1021/ma060668j)
  26. Hilker I, Rabani G, Verzijl Gerard KM, Palmans ARA, Heise A: Chiral polyesters by dynamic kinetic resolution polymerization. Angew. Chem. Int. Ed. 2006, 45, 2130-2132. (DOI: 10.1002/anie.200503496)
  27. Ten Breteler MR, Zhong Z, Dijkstra PJ, Palmans ARA, Peeters J, Feijen J: Ring-opening polymerization of substituted e-caprolactones with a chiral (salen) AlOiPr complex. J. Polym. Sci. Part A: Polym. Chem. 2006, 45, 429-436. (DOI:10.1002/pola.21841)
  28. van As BAC, Chan D-K, Kivit PJJ, Palmans ARA ,Meijer EW: Convenient double-enzymatic synthesis of both enantiomers of 6-methyl-e-caprolactone. Tetrahedron: Asymmetry, 2007, 18, 787-790. (DOI:10.1016/j.tetasy.2007.03.016)
  29. van Buijtenen J, van As BAC, Verbruggen M, Roumen L, Vekemans JAJM, Pieterse K, Hilbers PAJ Hulshof LA, Palmans ARA, Meijer EW: Switching from S- to R-selectivity in the Candida antarctica Lipase B-catalyzed ring-opening of w-methylated Lactones: tuning polymerizations by ring size. J. Am. Chem. Soc. 2007, 129, 7393–7398. (DOI: 10.1021/ja071241a)
  30. Palmans ARA, Meijer EW: Amplification of chirality in dynamic supramolecular assemblies. Angew. Chem. Int. Ed. 2007, 46, 8948–8968. (DOI:10.1002/anie.200701285)
  31. Wisse E, Renken R, Roosma J, Palmans ARA, Meijer EW: Poly(caprolactone-co-oxo crown ether) based poly(urethane)urea for soft tissue engineering applications. Biomacromolecules 2007, 8, 739–2745. (DOI:10.1021/bm070375d)
  32. van Beek DJM, Gillissen AJ, van As BAC, Palmans ARA, Sijbesma RP: Supramolecular copolyesters with tunable properties. Macromolecules 2007, 40, 6340–6348. (DOI: 10.1021/ma0705927)
  33. van As BAC, van Buijtenen J, Mes T, Palmans ARA, Meijer EW: Iterative tandem catalysis of secondary diols and diesters to chiral polyesters. Chem. Eur. J. 2007, 13, 8325-8332. (DOI: 10.1002/chem.200700818)
  34. Veld MAJ, Hult K, Palmans ARA, Meijer EW: Fast DKR of amines using isopropyl methoxyacetate as acyl donor. Eur. J. Org. Chem.2007, 5416-5421. (DOI: 10.1002/ejoc.200700568)
  35. Veld MAJ, Palmans ARA, Meijer EW: Selective polymerization of functional monomers with Novozym 435. J. Polym. Sci. Part A: Polym. Chem.2007, 45, 5968-5978. (DOI: 10.1002/pola.22350)
  36. Nallani M, de Hoog H-P, Cornelissen JJLM, Palmans ARA, van Hest J, Nolte RJM: Polymersome nanoreactors for enzymatic ring opening polymerization. Biomacromolecules 2007, 8, 3723–3728. (DOI:10.1021/bm7005938)
  37. Roosma J, Mes T, Leclere Ph, Palmans ARA, Meijer EW: Supramolecular materials from benzene-1,3,5-tricarboxamide based nanorods. J. Am. Chem. Soc.2008, 130, 1120–1121. (DOI: 10.1021/ja0774764)
  38. Xiao Y, Cummins D, Palmans ARA, Koning CE, Heise A: Synthesis of biodegradable chiral polyesters and microspheres by asymmetric enzymatic polymerization. Soft Matter2008, 4, 593-599. (DOI:10.1039/B717059A)
  39. Kanca U, van Buijtenen J, van As BAC, Korevaar P, Vekemans JAJM, Palmans ARA, Meijer EW: Iterative tandem catalysis of AB monomers. J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 2721-2733. (DOI: 10.1002/pola.22605)
  40. de Greef TFA, Nieuwenhuizen M, Stals PJM, Palmans ARA, Sijbesma RP, Meijer EW: The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents. Chem. Commun.2008, 4306–4308. (DOI: 10.1039/B806506C)
  41. Stals PJM, Haveman JF, Palmans ARA, Schenning APHJ: The self-assembly properties of a benzene-1,3,5-tricarboxamide derivative. J. Chem. Ed. 2009, 86, 230–232. (DOI: 10.1021/ed086p230)
  42. Stals PJM, Haveman JF, Martín-Rapún R, Fitié C, Palmans ARA, Meijer EW: The influence of oligo(ethylene glycol) side chains on the self-assembly of benzene-1,3,5-tricarboxamides in the solid state and in solution. J. Mater. Chem. 2009, 19, 124–130. (DOI: 10.1039/b816418e)
  43. Stals PJM, Smulders MMJ, Martín-Rapún R, Palmans ARA, Meijer EW: Asymmetrically substituted benzene-1,3,5-tricarboxamides: self-assembly and odd–even effects in the solid state and in dilute solution. Chem. Eur. J. 2009, 15, 2071–2080. (DOI: 10.1002/chem.2008021962071)
  44. Veld MAJ, Fransson L, Palmans ARA, Meijer EW, Hult K: Lactone size and reactivity in CALB: a molecular dynamic and docking study. ChemBioChem 2009, 10, 1330–1334. (DOI: 10.1002/cbic.200900128)
  45. Martín-Rapún R, Byelov D, Palmans ARA, de Jeu WH, Meijer EW: The lyotropic behavior of mixtures of C3-symmetrical discs and alkanes. Langmuir 2009, 25, 8794–8801. (DOI: 10.1021/la9003017)
  46. Smulders MMJ, Filot IAW, Leenders JMA, van der Schoot P, Palmans ARA, Schenning APHJ, Meijer EW: Tuning the extent of chiral amplification by temperature in a dynamic supramolecular polymer. J. Am. Chem. Soc. 2010, 132, 611–619. (DOI: 10.1021/ja908053d)
  47. Smulders MMJ, Stals PMJ, Mes T, Paffen T, Palmans ARA, Schenning APHJ, Meijer EW: Probing the limits of the Majority-Rules Principle in a dynamic supramolecular polymer. J. Am. Chem. Soc. 2010, 132, 620–626. (DOI: 10.1021/ja9080875)
  48. Stals PJM, Everts JC, de Bruijn R, Filot IAW, Smulders MMJ, Martín-Rapún R, Pidko EA, de Greef TFA, Palmans ARA, Meijer EW: Dynamic supramolecular polymers based on benzene-1,3,5-tricarboxamides: the influence of amide connectivity on aggregate stability and amplification of chirality. Chem. Eur. J. 2010, 16, 810–821. (DOI: 10.1002/chem.200902635)
  49. Mes T, Smulders MMJ, Palmans ARA, Meijer EW: Hydrogen-bond engineering in supramolecular polymers: polarity influence on the self-assembly of benzene-1,3,5-tricarboxamides. Macromolecules 2010, 43, 1981–1991. (DOI: 10.1021/ma9026096)
  50. Besenius P, Portale G, Janssen HM, Palmans ARA, Meijer EW: Controlling the size of one dimensional columnar self-assembled supramolecular polymers in water. Proc. Natl. Acad. Sci. USA 2010, 107, 17888–17893. (DOI: 10.1073/pnas.1009592107)
  51. Filot IAW, Palmans ARA, Hilbers PAJ, van Santen RA, Pidko EA, de Greef TFA: Understanding Cooperativity in Hydrogen Bond Induced Supramolecular Polymerization: A Density Functional Theory Study. J. Phys. Chem. B2010, 114, 13667–13674. (DOI: 10.1021/jp1072928)
  52. Terashima T, Mes T, De Greef TFA, Gillissen MAJ, Besenius P, Palmans ARA, Meijer EW: Single-Chain Folding of Polymers for Catalytic Systems in Water. J. Am. Chem. Soc. 2011, 133, 4742–4745. (DOI: 10.1021/ja2004494)
  53. Mes T, van der Weegen R, Palmans ARA, Meijer EW: Single-Chain Polymeric Nanoparticles by Stepwise Folding. Angew. Chem. Int. Ed. 2011, 22, 5085–5089. (DOI: 10.1002/anie.201100104)
  54. Wegner M, Dudenko D, Graf R, Spiess, H-W, Sebastiani D, Palmans ARA, de Greef TFA: The impact of amide connectivity on the assembly and dynamics of benzene-1,3,5-tricarboxamides in the solid state Chem. Sci. 2011, 2, 2040–2049. (DOI: 10.1039/C1SC00280E)
  55. Cantekin S, Palmans ARA: Pushing the limits of amplification of chirality in benzene-1,3,5-tricarboxamides. Chimica Oggi 2011, 29, 36–38.
  56. Besenius P, Goedegebure Y, Driesse M, Koay M, Bomans PHH, Palmans ARA, Dankers PYW, Meijer EW: Peptide Functionalised Discotic Amphiphiles and Their Self-Assembly into Supramolecular Nanofibres Soft Matter 2011, 7, 7980–7983. (DOI: 10.1039/C1SM05896G)
  57. Smulders MMJ, Nieuwenhuizen MML, Grossman M, Filot IAW, Lee CC, de Greef TFA, Schenning APHJ, Palmans ARA, Meijer EW: Cooperative Two-Component Self-Assembly of Mono- and Ditopic Monomers. Macromolecules 2011, 44, 6581–6587. (DOI: 10.1021/ma201255q)
  58. Gillissen MAJ, Hoeben TT, Spiering J, Vekemans JAJM, Palmans ARA, Meijer EW: Hierarchical self-assembly of ambiguous N,N’-bis-(bipyridyl)N’’-alkyl-BTA discotics: Competing cooperative and isodesmic self-assembly. Israel J. Chem. 2011, 51, 1118–1127. (DOI: 10.1002/ijch.201100063)
  59. Balkenende DWR, Cantekin S, Duxbury Ch, van Genderen MHP, Meijer EW, Palmans ARA: Enantioselective synthesis of (R)- and (S)-1-2H-1-octanol and their corresponding amines. Synth. Commun. 2012, 42, 563–573. (DOI: 10.1080/00397911.2010.527422)
  60. Nakano Y, Hirose T, Stals PJM, Meijer EW, Palmans ARA: Conformational analysis of supramolecular polymerization processes of disc-like molecules Chem. Sci. 2012, 3, 148–155. (DOI: 10.1039/c1sc00547b)
  61. Mes T, Scalfani V, Bailey T, Meijer EW, Palmans ARA: Network formation by orthogonal self-assembly. ACS MacroLett. 2012, 1, 105–109. (DOI: 10.1021/mz200108a)
  62. Stals PJM, Phang T, Gigmes D, Paffen TFE, Meijer EW, Palmans ARA: Nitroxide-mediated controlled radical polymerizations of styrene derivatives. J. Polym. Sci. Part A: Polym. Chem. 2012, 50, 780–791. (DOI: 10.1002/pola.25833)
  63. Besenius P, Palmans ARA: Controlling the size, shape and stability of supramolecular polymers in water. J. Visual Exp. 2012, 66, e3975. (DOI 10.3791/3975).
  64. Cantekin S, Nakano Y, Everts JC, Meijer EW, Palmans ARA: A stereoselectively deuterated supramolecular motif to probe the role of solvent during self-assembly processes. Chem. Commun. 2012, 48, 3803–3805. (DOI: 10.1039/c2cc17284d)
  65. Wang F, Gillissen MAJ, Stals PJM, Palmans ARA, Meijer EW: Hydrogen bonding directed supramolecular polymerization of oligo(phenylene-ethynylene)s: cooperative mechanism, core symmetry effect, and chiral amplification. Chem. Eur J. 2012, 18, 11761–11770. (DOI: 10.1002/chem.201200883)
  66. Cantekin S, ten Eikelder HMM, Markvoort AJ, Veld MAJ, Korevaar P, Green MM, Palmans ARA, Meijer EW: Consequences of cooperativity in racemizing supramolecular systems. Angew. Chem. Int. Ed. 2012, 51, 6426–6431. (DOI: 10.1002/anie.201201701)
  67. Schaefer C, Voets I, Palmans ARA, van der Schoot P, Besenius P, Meijer EW: Controlling the cooperativity in the supramolecular polymerisation of ionic discotic amphiphiles via electrostatic screening. ACS MacroLett. 2012, 1, 830–833. (DOI: 10.1021/mz300218e)
  68. Cantekin S, de Greef TFA, Palmans ARA: Benzene-1,3,5-tricarboxamides: a versatile ordering moiety in supramolecular chemistry. Chem. Soc. Rev. 2012, 41, 6125–6137. (DOI: 10.1039/c2cs35156k)
  69. Gillissen MAJ, Meijer EW, Voets IK, Palmans ARA: Single chain polymeric nanoparticles as compartmentalised sensors for metal ions. Polym. Chem. 2012, 3, 3166–3174. (DOI: 10.1039/C2PY20350B)
  70. Filot IAW, Palmans ARA,. Hilbers PA, Hensen EJM, de Greef TFA, Pidko EA: The origin of isotope-induced chirality in supramolecular polymers of benzene-1,3,5-tricarboxamides. Phys. Chem. Chem. Phys. 2012, 14, 13997-14002. (DOI 10.1039/C2CP42302B)
  71. Stals PJM, Korevaar PA, Gillissen MAJ, de Greef TFA, Fitié CFC, Sijbesma RP, Palmans ARA, Meijer EW: Symmetry breaking in the self-assembly of partially fluorinated benzene-1,3,5-tricarboxamides. Angew. Chem. Int. Ed. 2012, 51, 11297–11301. (DOI: 10.1002/anie.201204727)
  72. Huerta E, Stals PJM, Meijer EW, Palmans ARA: Consequences of folding a water-soluble polymer around an organocatalyst. Angew. Chem. Int. Ed. 2013, 52, 2906–2910. (DOI: 10.1002/anie.201207123)
  73. Stals PJM, Gillissen MAJ, Nicolaÿ R, Meijer EW, Palmans ARA: The balance between intramolecular hydrogen bonding, polymer solubility and rigidity in single-chain polymeric nanoparticle. Polym. Chem. 2013, 4, 2584–2597. (DOI: 10.1039/C3PY00094J)
  74. Leenders CA, Albertazzi L, Koenigs M, Palmans ARA, Meijer EW: Supramolecular polymerization in water by both hydrophobic effects and hydrogen bond formation. Chem. Commun. 2013, 49, 1963–1965. (DOI: 10.1039/C3CC38949A)
  75. Hosono N, Gillissen MAJ, Li Y, Sheiko S, Palmans ARA, Meijer EW: Orthogonal self-assembly in folding block copolymers. J. Am. Chem. Soc. 2013, 135, 501–510. (DOI: 10.1021/ja310422w)
  76. Stals PJM, Li Y, Burdyńska J, Nicolaÿ R, Nese A, Palmans ARA, Meijer EW, Matyjaszewski K, Sheiko SS: How far can we push polymer architectures? J. Am. Chem. Soc. 2013, 2013, 135, 11421–11424. (DOI: 10.1021/ja400890v)
  77. Gillissen MAJ, Terashima T, Kohlbrecher J, Meijer EW, Palmans ARA, Voets IK:Sticky supramolecular grafts stretch single polymer chains. Macromolecules, 2013, 46, 4120–4125. (DOI: 10.1021/ma4006846)
  78. Mes T, Cantekin S, Balkenende DWR, Frissen MMM, Gillissen MAJ, Voets IK, Meijer EW, Palmans ARA: Thioamides: versatile bonds to induce directional and cooperative H-bonding in supramolecular polymers. Chem. Eur. J. 2013, 19, 8642–8649. (DOI: 10.1002/chem.201204273)
  79. Garcia F, Korevaar P, Verlee A, Meijer EW, Palmans ARA, Sánchez L: The influence of p-conjugated moieties on the thermodynamics of cooperatively self-assembling tricarboxamides. Chem. Commun. 2013, 49, 8674–8676. (DOI: 10.1039/C3CC43845G)
  80. Nakano Y, Markvoort AJ, Cantekin S, Filot IAW, ten Eikelder HMM, Meijer EW, Palmans ARA: Conformational analysis of chiral supramolecular aggregates: modelling the subtle difference between hydrogen and deuterium. J. Am. Chem. Soc. 2013, 135, 16497–16506. (DOI: 10.1021/ja4073645)
  81. de Feijter I, Besenius P, Albertazzi L, Meijer EW, Palmans ARA, Voets IK: Mechanistic control over morphology: self-assembly of a discotic amphiphile in water. Soft Matter 2013, 9, 10025–10030. (DOI: 10.1039/c3sm52104d)
  82. Artar M, Terashima T, Sawamoto M, Meijer EW, Palmans ARA: Understanding the catalytic activity of single-chain polymeric nanoparticles in water. J. Polym. Sci. A: Polym. Chem. 2014, 52, 12–20. (DOI: 10.1002/pola.26970)
  83. Leenders CMA, Mes T, Baker MB, Koenigs MME, Besenius P, Palmans ARA, Meijer EW: From supramolecular polymers to hydrogel materials. Mater. Horiz. 2014, 1, 116–120. (DOI: 10.1039/c3mh00103b
  84. Gillissen MAJ, Koenigs MME, Spiering AJH., Vekemans JAJM, Voets IK, Palmans ARA, Meijer EW: Triple helix formation in amphiphilic discotics: demystifying solvent effects in supramolecular self-assembly. J. Am. Chem. Soc. 2014, 136, 336–343. (DOI: 10.1021/ja4104183)
  85. Hosono N, Stals PJM, Palmans ARA, Meijer EW: Consequences of block sequence on the orthogonal folding of triblock copolymers. Chem. Asian J. 2014, 9, 1099–1107. (DOI: 10.1002/asia.201400011)
  86. Hosono N, Pitet LM, Palmans ARA, Meijer EW: The effect of pendant benzene-1,3,5-tricarboxamides in the middle block of ABA triblock copolymers: synthesis and mechanical properties.  Polym. Chem. 2014, 5, 1463–1470. (DOI: 10.1039/C3PY01189)
  87. Stals PJM, Gillissen MAJ, Paffen TFE, de Greef TFA, Lindner P, Meijer EW, Palmans ARA, Voets IK: Folding polymers with pendant hydrogen bonding motifs in water: the effect of polymer length and concentration on the shape and size of single-chain polymeric nanoparticles. Macromolecules 2014, 47, 2947–2954. (DOI: 10.1021/ma500273g)
  88. Huerta E, van Genabeek B, Stals PJM, Meijer EW, Palmans ARA: A modular approach to introduce function into single chain polymeric nanoparticles. Macromol. Rapid Commun. 2014, 35, 1320–1325. (DOI: 10.1002/marc.201400213) 
  89. Appel WPJ, Nieuwenhuizen MML, Lutz M, de Waal BFM, Palmans ARA, Meijer EW: Supramolecular chemistry with ureido-benzoic acids. Chem. Sci. 2014, 5, 3735–3745. (DOI: 10.1039/C4SC00871E)
  90. Hosono N, Palmans ARA, Meijer EW: “Soldier–Sergeant–Soldier” triblock copolymers reveal folding structures of single-chain polymeric nanoparticles. Chem. Commun. 2014, 50, 7990–7993. (DOI: 10.1039/c4cc02789b)
  91. Teunissen AJP, Nieuwenhuizen MML, Rodríguez-Llansola F, Palmans ARA, Meijer EW: Mechanically-induced gelation of a kinetically trapped supramolecular polymer. Macromolecules 2014, 47, 8429–8436. (DOI: 10.1021/ma502047h)

Contributions to books

  1. Palmans ARA, van As BAC, van Buijtenen J and Meijer EW: Ring-opening of -substituted lactones by Novozym 435: selectivity issues and application to iterative tandem catalysis. ACS Symp. Ser. 2008, 999 (Polymer Biocatalysis and Biomaterials II, Eds H Cheng and RA Gross): p. 230.
  2. de Geus M, Palmans ARA, Duxbury CJ, Villarroya S, Howdle SM and Heise A: Chemo-enzymatic synthesis of block copolymers. ACS Symp. Ser., 2008, 999 (Polymer Biocatalysis and Biomaterials II, Eds H Cheng and RA Gross): p. 216.
  3. Heise A, Duxbury CJ and Palmans ARA: Handbook of ring-opening polymerizations. Chapter 15: Enzyme-Mediated ROP 2009, Eds. Dubois P, Coulembier O, Raquez J-M: p. 379.
  4. Veld MAJ and Palmans ARA: Hydrolases part I: Enzyme mechanism, selectivity and control in the synthesis of well-defined polymers. Springer Verlag, Advances in Polymer science: Enzymatic polymerizations. Eds. Palmans ARA and Heise A 2010, 237: p. 55.
  5. Heise A and Palmans ARA: Hydrolases part II: Chemo-enzymatic approaches to polymeric materials. Springer Verlag, Advances in Polymer science: Enzymatic polymerizations. Eds. Palmans ARA and Heise A, 2010, 237: p. 79.
  6. Veld MAJ and Palmans ARA: Chiral polymers by lipase catalysis. Wiley, Polymers by Biocatalysis. 2010, Ed. Loos K: p. 277.
  7. Artar M, Huerta E, Meijer EW and Palmans ARA: Dynamic single chain polymeric nanoparticles: from structure to function. ACS Symp. Ser., 2014, 1170 (Sequence-Controlled Polymers: Synthesis, Self-Assembly, and Properties, Eds JF Lutz, TY Meyer, M Ouchi and M Sawamoto): p. 313
  8. Artar M and Palmans ARA: Chapter 5: Catalysis inside folded single macromolecules in water. Springer, 2017, Ed. R Poli in Effects of nanoconfinement on catalysis (Series: Fundamental and Applied Catalysis): p. 105
  9. Liu Y and Palmans ARA: Chapter 5. Dynamically folded single-chain polymeric nanoparticles. Wiley, 2017, Ed. JA Pomposo in Single-Chain Polymer Nanoparticles: Synthesis, Characterization, Simulations and Applications: p. 183
  10. Palmans ARA: Chapter 28: Single chain polymeric nanoparticles: towards in vivo imaging and catalysis in complex media. Elsevier, 2018, Eds. HS Azevedo and RMP da Silva in Molecular Design, Characterization and Application in Biology and Medicine

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